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  • MBA.Graduate Psychology,PHD in HRM
    Strayer,Phoniex,
    Feb-1999 - Mar-2006

  • MBA.Graduate Psychology,PHD in HRM
    Strayer,Phoniex,University of California
    Feb-1999 - Mar-2006

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Category > Chemistry Posted 20 Aug 2017 My Price 10.00

Organic chemistry questions

QUESTION 1

1.      A molecule with the general structure RCO2COR' would be named as a(n) :

 

 

carboxylic acid

 

 

acid anhydride

 

 

acid halide

 

 

amide

QUESTION 2

1.      Alpha helices form a coiled structure due to:

 

 

covalent linkages

 

 

salt bridges

 

 

ionic interactions

 

 

hydrogen bonds

QUESTION 3

1.      Amides are strong bases.

  True

  False

QUESTION 4

1.      CH3(CH2)3-Cl + sodium hydrosulfide will form:

 

 

alcohol

 

 

alkene

 

 

thiol

 

 

ether

QUESTION 5

1.      If (S)-2-ethyl-1-hexanol has a specific rotation of -20.05 degrees, what is the specific rotation of (R)-2-ethyl-1-hexanol ?

 

 

It must be experimentally determined.

 

 

0 degrees

 

 

-20.05 degrees

 

 

20.05 degrees

QUESTION 6

1.      In a carbocation, the positively charged carbon atom would have what type of hybridization ?

 

 

SP3

 

 

SP2

 

 

SP

 

 

P

QUESTION 7

1.      In the addition of HX to an alkene

 

 

the H will add to the most substituted carbon

 

 

the newly formed double bond will not be conjugated

 

 

the newly formed double bond will be conjugated

 

 

the X will add to the most substituted carbon

QUESTION 8

1.      IR spectroscopy is used to detect functional groups.

  True

  False

QUESTION 9

1.      L sugars are levorotatory.

  True

  False

QUESTION 10

1.      Primary alcohols can be converted into aldehydes by using:

 

 

Grignard reagent

 

 

Tollens reagent

 

 

PCC

 

 

KMNO4

QUESTION 11

1.      Reacting an acid halide with an alcohol in pyridine yields

 

 

an ether

 

 

a carboxylic acid

 

 

an acid anhydride

 

 

an ester

QUESTION 12

1.      Reacting an acid halide with water will result in:

 

 

esters

 

 

carboxylic acids

 

 

ketones

 

 

primary alcohol

QUESTION 13

1.       Suppose you have no sense of smell, and you want to know if the person who shares your lab bench put some acetic acid in your ethanol. You put a sample of your solution in an IR spectrophotometer and you see a peak at 1695 cm-1. You now know that you should...

 

 

... quit being so paranoid, they didn't mix things up.

 

 

... stop making mixed drinks out of of lab reagents, there's acid in there!

QUESTION 14

1.      Tertbutylcyclohexane is most stable with the substituent in the _______ conformation.

 

 

axial

 

 

cis

 

 

equitorial

 

 

trans

QUESTION 15

1.      Tertiary alkyl halides will react by E2

 

 

will not react by E2

 

 

under basic conditions

 

 

under neutral conditions

 

 

under acidic conditions

QUESTION 16

1.      The instability of cyclopropane is due to:

 

 

angle strain

 

 

steric clash

 

 

highly reactive functional group

 

 

none of the above

QUESTION 17

1.      The larger the Ka, the smaller the pKa.

  True

  False

QUESTION 18

1.      The pI of an amino acid is equal to the pKa of the side chain.

  True

  False

QUESTION 19

1.      The reaction of a aldehyde with a Grignard reagent will form:

 

 

tertiary alcohols

 

 

carboxylic acids

 

 

secondary alcohols

 

 

primary alcohols

QUESTION 20

1.      The reaction of a ketone with an alcohol in acidic conditions will result in:

 

 

an acetal

 

 

an alkene

 

 

an alkane

 

 

a geminal (gem) diol

 

QUESTION 21

1.      The reaction of CH3CH=CH2 with HCl will form:

 

 

1-propanol

 

 

2-chloropropane

 

 

1-chloropropane

 

 

2-propanol

QUESTION 22

1.      Treatment of an aldehyde with NaBH4 yields

 

 

an ester

 

 

a carboxylic acid

 

 

an alcohol

 

 

an ether

QUESTION 23

1.      Ultraviolet spectroscopy can be used to detect

 

 

bond vibration

 

 

ion mass

 

 

pi electron structure

 

 

hydrogen environment

QUESTION 24

1.      What is the hybridization of the carbon of a methyl group ?

 

 

sp

 

 

s3p2

 

 

sp2

 

 

sp3

QUESTION 25

1.      Which are constitutional isomers ?

 

 

(E)-2-hexene and (Z)-2-hexene

 

 

hexanal and 2 hexanone

 

 

(R)-2-chlorobutane and (S)-2-chloropropane

 

 

1-bromobutane and 1-bromoethane

QUESTION 26

1.      Which compound has the strongest carbon sigma bond?

 

 

acetylene

 

 

methane

 

 

ethane

 

 

ethylene

QUESTION 27

1.      Which general formula describes an alkene with 1 double bond?

 

 

CnH2n-2

 

 

CnH2n-1

 

 

CnH2n+2

 

 

CnH2n

QUESTION 28

1.      Which is a pair of diastereomers ?

 

 

(S,R) and (R,S)

 

 

(R,S) and (S,R)

 

 

(R,R) and (S,S)

 

 

(S,S) and (R,S)

QUESTION 29

1.      Which of the following molecules would you expect to have the highest melting point?

 

 

pentane

 

 

methane

 

 

butane

 

 

1-pentanol

 

QUESTION 30

1.      Which statement best describes the mechanism of the SN1 reaction ?

 

 

back-side attack with inversion of configuration

 

 

front-side attack with inversion of configuration

 

 

back-side attack with retention of configuration.

 

 

front-and-back side attack with racemization

 

 

Answers

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Status NEW Posted 20 Aug 2017 01:08 PM My Price 10.00

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