Ozone, O3(g), is an unstable allotrope of oxygen and it gradually converts to the regular oxygen gas, O2(g). A possible mechanism for this decomposition is as follows.

 

 

                k1

(1) O3(g) ⇄ O2(g) + O(g) Fast

                k-1

 

                 k2

(2) 2 O(g) → O2(g) Slow

 

a) Write the overall reaction equation for the conversion of O3(g) into O2(g). Again, note that this may not necessarily be a simple sum of steps; some steps may occur multiple times.

b) Using the pre-equilibrium approach, write the rate law for this reaction based on the above mechanism.

c) What species is the intermediate in this mechanism?

d) Based on the rate law, is there an inhibitor in this mechanism?

e) What is the overall order of the reaction based on this mechanism?

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