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MBA.Graduate Psychology,PHD in HRM
Strayer,Phoniex,
Feb-1999 - Mar-2006
MBA.Graduate Psychology,PHD in HRM
Strayer,Phoniex,University of California
Feb-1999 - Mar-2006
PR Manager
LSGH LLC
Apr-2003 - Apr-2007
Shown are the quantities of solutions and water that constitute the six runs or separate experiments
Run # |
0.090 M KI |
1.0 M H2O2 |
H20 |
Total Volume |
1 |
10 |
5 |
15 |
30 |
2 |
10 |
5 |
15 |
30 |
3 |
10 |
10 |
10 |
30 |
4 |
20 |
5 |
5 |
30 |
5 |
20 |
10 |
0 |
30 |
6 |
10 |
5 |
15 |
30 |
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I need help with the calculation of the best rate calculation and the questions in the post-lab. I have attached the data from the runs that were performed
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Please show calculations for the best value for the observed rate of O2 production in mL O2/min for the following runs.
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These are the data from the runs
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Run 1
Water level (mL) |
Time (sec) |
47.6 |
30 |
45.5 |
60 |
43.4 |
90 |
41.4 |
120 |
39.3 |
150 |
37.6 |
180 |
35.5 |
210 |
33.8 |
240 |
31.7 |
270 |
30.3 |
300 |
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Run 2
Water level (mL) |
Time (sec) |
47.9 |
30 |
45.9 |
60 |
43.7 |
90 |
41.1 |
120 |
38.0 |
150 |
35.7 |
180 |
33.6 |
210 |
31.4 |
240 |
29.1 |
270 |
27.0 |
300 |
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Run 3
Time (sec) |
Water level (mL) |
30 |
46.5 |
60 |
42.6 |
90 |
37.7 |
120 |
32.6 |
150 |
27.9 |
180 |
23.5 |
210 |
20.3 |
240 |
16.5 |
270 |
12.1 |
300 |
8.2 |
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Run 4
Time (sec) |
Water level (mL) |
30 |
44 |
60 |
37.5 |
90 |
32 |
120 |
27.3 |
150 |
22.1 |
180 |
18.5 |
210 |
15.2 |
240 |
13 |
270 |
10 |
300 |
7.2 |
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Run 5
Time (sec) |
Water level (mL) |
30 |
39.5 |
60 |
30.5 |
90 |
23.6 |
120 |
16.6 |
150 |
9.5 |
180 |
4.2 |
210 |
0 |
240 |
0 |
270 |
0 |
300 |
0 |
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Run 6
Time (sec) |
Water level (mL) |
30 |
47.2 |
60 |
44.7 |
90 |
42.6 |
120 |
40.7 |
150 |
37.5 |
180 |
34.2 |
210 |
30.8 |
240 |
26.8 |
270 |
24.1 |
300 |
20.5 |
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Run # |
[H2O2] initial |
[KI] initial |
Temp (in C) |
Best rate |
1 |
0.167 |
0.030 |
21.4 |
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2 |
 0.167 |
0.030 |
20.7 |
 |
3 |
0.333 |
0.030 |
22.9 |
 |
4 |
0.167 |
0.06 |
22.9 |
 |
5 |
0.333 |
0.06 |
22.9 |
 |
6 |
0.167 |
0.030 |
42.3 |
 |
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Post-lab Questions
1)Â Â Â Describe how you arrive at the best rate for each run. Consider these questions in your answer: are the rates the same all the same in a given run? Should they be? Are the rates consistent within a run and between runs?
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2)Â Â Â Using the differences in initial concentrations and rate that you observed in runs 2 through 5, write the rate-law expression for the decomposition of H2O2. Explain how you arrived at your rate-law expression.
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3)Â Â Â If your rate is expressed as a change in molar concentration per second (M/s), what are the units for the rate constant (k). Hint the units for k can be anything; think about what units need to be cancelled out in order to achieve the proper rate unit M/s
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4) How does temperature affect the reaction rate? Explain using your data and propose a hypothesis to explain the effect.Â
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