Three of the forms of elemental carbon are graphite, diamond,and buckminsterfullerene. The entropies at 298 K for graphite and diamond are listed in Appendix C. (a) Account for the difference in the S° values of graphite and diamond in light of their structures (Figure 12.30). (b) What would you expect for S° the value of buckminsterfullerene (Figure 12.47) relative to the values for graphite and diamond? Explain.

Figure 12.30

Figure 12.47

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