Maurice Tutor

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    Argosy University/ Phoniex University/
    Nov-2005 - Oct-2011

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    Phoniex University
    Oct-2001 - Nov-2016

Category > Management Posted 02 Oct 2017 My Price 5.00

hexacyanoruthenate

The concentrations of Fe3+ and Cu2+ in a mixture can be determined following their reaction with hexacyanoruthenate (II), Ru(CN)64–, which forms a purple blue complex with Fe3+ (l? max = 550 nm), and a pale green complex with Cu2+ ( ? max = 396 nm). The molar absorptivities (M–1 cm–1) for the metal complexes at the two wavelengths are summarized in the following table.

e550 e396

Fe3+ 9970 84

Cu2+ 34 856

When a sample containing Fe3+ and Cu2+ is analyzed in a cell with a path length of 1.00 cm, the absorbance at 550 nm is 0.183, and the absorbance at 396 nm is 0.109. What are the molar concentrations of Fe3+ and Cu2+ in the sample?

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Status NEW Posted 02 Oct 2017 01:10 PM My Price 5.00

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