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MCS,PHD
Argosy University/ Phoniex University/
Nov-2005 - Oct-2011
Professor
Phoniex University
Oct-2001 - Nov-2016
7.54Â Â Â 3Consider a binary mixture of species a and species b at 300 K and 1 bar. The vapor pressure of pure a at 300 K is 80 kPa. A plot of the activity coefficient of species a vs. mole fraction of species a is shown below. Based on this plot,
(a)    Specify the reference state for species a (Lewis-Randall or Henry’s). Explain.
(b)Â Â Â Â What is the value of fa?
(c)Â Â Â Â What is the value of Ha?
(d)Â Â Â As best as you can, come up with the Margules parameter A in the two-suffix Margules equation
gE 5 Axaxb
(e)Â Â Â Â Consider a liquid mixture of 2 moles of a and 3 moles of b at 300 K and 1 bar. At equilibrium, what is the mole fraction of a in the vapor phase, ya?
(f)Â Â Â Â Â For the mixture above, determine gb based on a Lewis/Randall reference state.
Â
Â
3
2.75
2.5
2.25
2
1.75
1.5
1.25
1
0.75
0.5
0.25
0
Â
Â
Â
|
Activity coefficient of species a
0Â Â Â Â Â 0.1Â Â Â Â 0.2Â Â Â 0.3Â Â Â 0.4Â Â Â Â 0.5
xa
Â
0.6Â Â Â 0.7Â Â Â 0.8Â Â Â Â 0.9Â Â Â Â Â 1
Â
Â
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